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Microelectrode Modification by Spark Discharge

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HRBÁČ Jan ROSZYPAL Jan RIMAN Daniel HALOUZKA Vladimír

Rok publikování 2016
Druh Článek ve sborníku
Konference XXXVI MODERNI ELEKTROCHEMICKE METODY
Fakulta / Pracoviště MU

Přírodovědecká fakulta

Citace
www https://www.bestservis.eu/upload/file/Sbornik_metody16.pdf
Klíčová slova Electric discharge; Spark deposition; Metal electrodes; Carbon fiber Microelectrode
Popis The direct current electrical spark discharge between the two electrodes, one being the source of the amterial and the second a substrate (target) onto which the material is deposited is shown to be very effective method of eelctrode modification. The method is introduced for metal eelctrodes as amterial source and carbon fiber microelectrode. Soecifically, gold is deposited onto carbon fiber in he form of nanoparticles when the spark discharge occurs after bringing into close proximity the gold electrode connected to negative pole and carbon fiber microelectrode to the positive pole of the power supply, delivering 900 V. The utility of carbon fiber modified this way with gold for stripping voltammetry of arsenic is demonstrated.

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