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Copper(II) oxalate and oxamate complexes
Autoři | |
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Rok publikování | 2000 |
Druh | Článek v odborném periodiku |
Časopis / Zdroj | Transition Metal Chemistry |
Fakulta / Pracoviště MU | |
Citace | |
Obor | Anorganická chemie |
Klíčová slova | X-RAY STRUCTURE; MAGNETIC-PROPERTIES; OXAMIC ACID; MU-OXAMIDO; LIGANDS; CRYSTAL; BRIDGES |
Popis | Reaction of Cu-II salts with phenanthroline and oxalate (ox) or oxamate (oxm) gives [Cu(phen)(ox)(H2O)] . H2O or [Cu(phen)(oxm)(H2O)] . H2O complexes while direct treatment of Cu-II salts with oxalate or oxamate gives [NH4](2)[Cu(ox)(2)] and [Cu(oxm)(2)(H2O)(2)] respectively. The X-ray structures of one example of each system, aquo-oxamato-phenanthroline-copper(II)-dihydrate and the polymeric ammonium-bis(aquo)-tetraoxalato-dicopper(II)-dihydrate, are reported. |
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