Informace o publikaci
[N-(Carboxylatomethyl)aspartato(3-)](ethylenediamine)cobalt(III) trihydrate
| Autoři | |
|---|---|
| Rok publikování | 2003 |
| Druh | Článek v odborném periodiku |
| Časopis / Zdroj | Acta Crystallographica Section C: Crystal Structure |
| Fakulta / Pracoviště MU | |
| Citace | |
| Obor | Anorganická chemie |
| Klíčová slova | structure; cobalt(III) |
| Popis | The mononuclear title complex, [Co(C6H6NO6)(C2H8N2)].3H2O, contains an octahedrally coordinated Co(III) atom. The N-(carboxymethyl)aspartate moiety is coordinated as a tetradentate ligand, providing an OONO-donor set and forming two trans five-membered chelate rings and one six-membered chelate ring. A seven-membered chelate ring is also formed, which consists of part of the six-membered chelate ring and part of one of the five-membered chelate rings. The crystal structure of the complex is stabilized by hydrogen bonds with three water molecules. |
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