Informace o publikaci
Inclusion complexes between 3,3-substituted [n]staffanes and beta-cyclodextrin in water.
| Název česky | Inclusion complexes between 3,3-substituted [n]staffanes and b-cyclodextrin in water. |
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| Autoři | |
| Rok publikování | 2004 |
| Druh | Článek ve sborníku |
| Konference | Chemické listy |
| Fakulta / Pracoviště MU | |
| Citace | |
| www | http://www.vscht.cz/chem_listy/ |
| Obor | Organická chemie |
| Klíčová slova | bicyclopentanes; staffanes; cyclodextrin; NMR |
| Popis | Axially substituted [n]staffanes I form inclusion complexes with â-cyclodextrin (II) in water. 1H NMR spectrum of a water solution of beta-cyclodextrin II has shown apparent changes of chemical shifts of intracavity protons H-3 and H-5 upon addition of [2]staffane-3,3-diol (Ia)into the solution. Nuclear Overhauser effect has been observed between beta-cyclodextrin protons H-3, H-5 and bridge protons of the diol Ia. The method of continuous variations applied to the both complexation sensitive chemical shifts revealed formation of host-guest complex of 1:1 stoichiometry. |
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