Project information
New cucurbit[n]uril derivates
- Project Identification
- GP203/07/P382
- Project Period
- 1/2007 - 12/2009
- Investor / Pogramme / Project type
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Czech Science Foundation
- Postdoctoral projects
- MU Faculty or unit
- Faculty of Science
- Keywords
- cucurbituril, supramolecular chemistry, molecular recognition
This project will investigate the preparation of new cucurbit[n]uril derivates. Different factor which influence the composition and size of the macrocycles will be studied including choice and ratio of starting materials, type of solvent and reaction temperature. Suitable separation technique will be found to obtain desired cucurbit[n]uril derivative. In order to determine the influence of macrocycle modification on its binding properties the stability constants of complexes between cucurbit[n]uril derivatives and different guest molecules will be measured. The supramolecular polyvalent systems will be prepared using reactions between selected cucurbit[n]uril derivatives and polymers or oligomers.
Publications
Total number of publications: 19
2011
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Nové makrocyklické deriváty glykolurilu, způsob jejich přípravy a použití
Publisher: UPVCR Úřad průmyslového vlastnictví České republiky, state: Czech Republic, patent's number: 302710, year: 2011
2010
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Bambus[6]uril
Angewandte Chemie International Edition, year: 2010, volume: 49, edition: 13
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Reasons Why Aldehydes Do Not Generally Participate in Cucurbit[n]uril Forming Reactions
Journal of Organic Chemistry, year: 2010, volume: 75, edition: 9
2009
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Electron Density Shift in Imidazolium Derivatives upon Complexation with Cucurbit[6]uril
Chemistry - A European Journal, year: 2009, volume: 15, edition: 28, DOI
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Glycoluril Based Molecular Clips
Year: 2009, type: Conference abstract
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Glycoluril Trimers: Selective Synthesis and Supramolecular Properties
Organic Letters, year: 2009, volume: 11, edition: 18, DOI
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Charge Localization on Imidazolium Ring upon Complexation with Cucurbit[6]uril
Year: 2009, type: Conference abstract
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Localized Charge of Aromatic Sytems Caused by Complexation with Cucurbit[n]uril
Year: 2009, type: Conference abstract
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Makrocyklické látky na bázi glykolurilů jako možná plniva pro polopropustné polymerní membrány
Year: 2009, type: Conference abstract
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Modified Cucurbit[6]uril and its Supramolecular Interactions with Methylviologen
Year: 2009, type: Conference abstract