Publication details
Determination of Intrinsic Binding Modes by Mass Spectrometry: Gas-Phase Behavior of Adamantylated Bisimidazolium Guests Complexed to Cucurbiturils
| Authors | |
|---|---|
| Year of publication | 2012 |
| Type | Article in Periodical |
| Magazine / Source | Chemistry - A European Journal |
| MU Faculty or unit | |
| Citation | |
| Web | http://onlinelibrary.wiley.com/doi/10.1002/chem.201201444/epdf |
| Doi | http://dx.doi.org/10.1002/chem.201201444 |
| Field | Biochemistry |
| Keywords | adamantane; cucurbituril; host–guest systems; imidazolium salts; supramolecular chemistry |
| Description | Adamantylated bisimidazolium cations exhibit a distinct fragmentation pathway in contrast to their cucurbit[7]uril (CB7) complexes. The observed alternative fragmentation of the guest molecule in a complex clearly correlates to the supposed sterically hindered or allowed slippage of the macrocycle over the axel molecule. |
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