Publication details
Syntheses and X-ray structures of heteroleptic octahedral Mn (II)-xanthato complexes involving N-donor ligands
| Title in English | Syntheses and X-ray structures of heteroleptic octahedral Mn(II)-xanthato complexes involving N-donor ligands |
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| Authors | |
| Year of publication | 2015 |
| Type | Article in Periodical |
| Magazine / Source | Journal of coordination chemistry |
| MU Faculty or unit | |
| Citation | |
| Doi | http://dx.doi.org/10.1080/00958972.2015.1102228 |
| Field | Inorganic chemistry |
| Keywords | Manganese(II) complexes; Crystal structures; Xanthates; Bipyridines; 1 10-Phenanthroline |
| Attached files | |
| Description | A series of octahedral manganese(II) complexes involving xanthates and N-donor ligands, [Mn (S(2)COiBu)(2)(phen)] (1), [Mn(S(2)COiBu)(2)(2,2'-bpy)] (2), [Mn(S(2)COnPr)(2)(phen)] (3), [Mn(S(2)COnPr)(2) (2,2'-bpy)] (4), [Mn(S2COMe)(2)(2,2'-bpy)] (5), [Mn(S(2)COnPr)(2)(4,4'-bpy)](n), and [Mn-2(S(2)COnPr)(4) (4,4'-bpy)(3)] (6) (phen = 1,10-phenanthroline, bpy - bipyridine) was prepared. Complexes were characterized by elemental analysis, FTIR spectroscopy, TG/DSC analysis, and single-crystal X-ray diffraction. The structures are built of monomeric molecules of the complexes, except for 6 with the 4,4'-bipyridine ligand, which contains a binuclear complex and 1D polymeric zigzag chain in one crystal. |