Publication details

Electrochemical behaviour of [N]helicenes

Authors

HRBÁČ Jan STORCH Jan TRNKOVÁ Libuše VACEK Jan

Year of publication 2016
Type Article in Proceedings
Conference XVI. Workshop of Physical Chemists and Electrochemists
MU Faculty or unit

Faculty of Science

Citation
Field Physical chemistry and theoretical chemistry
Keywords helicenes; cyclic voltammetry; glassy carbon electrode; indium tin oxide
Description Helicenes are ortho-condensed polycyclic aromatic compounds, in which benzene rings are angularly annulated to give helically-shaped molecules. The chemistry of helicenes attracts continuing attention because of their unique structural, spectral and optical features. Synthetic approaches are continuously developed allowing the syntheses of these unique compounds in higher amounts and with greater yields. The aim of this work is to investigate basic redox behaviour of [5]helicene, [6]helicene and [7]helicene in acetonitrile solutions using cyclic voltammetry.

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