Publication details

Investigation of Pristine Graphite Oxide as Room-Temperature Chemiresistive Ammonia Gas Sensing Material

Authors

BANNOV Alexander JAŠEK Ondřej ZAJÍČKOVÁ Lenka PRÁŠEK Jan

Year of publication 2017
Type Article in Periodical
Magazine / Source SENSORS
MU Faculty or unit

Central European Institute of Technology

Citation
Web web nakladatele
Doi http://dx.doi.org/10.3390/s17020320
Field Plasma physics
Keywords graphite oxide; chemiresistive gas sensor; sensitivity; ammonia
Attached files
Description Graphite oxide has been investigated as a possible room-temperature chemiresistive sensor of ammonia in a gas phase. Graphite oxide was synthesized from high purity graphite using the modified Hummers method. The graphite oxide sample was investigated using scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray diffraction, thermogravimetry and differential scanning calorimetry. Sensing properties were tested in a wide range of ammonia concentrations in air (10–1000 ppm) and under different relative humidity levels (3%–65%). It was concluded that the graphite oxide–based sensor possessed a good response to NH3 in dry synthetic air (dR/R0 ranged from 2.5% to 7.4% for concentrations of 100–500 ppm and 3% relative humidity) with negligible cross-sensitivity towards H2 and CH4. It was determined that the sensor recovery rate was improved with ammonia concentration growth. Increasing the ambient relative humidity led to an increase of the sensor response. The highest response of 22.2% for 100 ppm of ammonia was achieved at a 65% relative humidity level
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