Publication details

Luminescent complexes of Cu-I halides with functionalized tertiary phosphines

Authors

BARTOŠ Peter TÁBORSKÝ Petr NEČAS Marek

Year of publication 2016
Type Article in Periodical
Magazine / Source Phosphorus, Sulfur, and Silicon and the related elements
MU Faculty or unit

Faculty of Science

Citation
Doi http://dx.doi.org/10.1080/10426507.2015.1128926
Field Inorganic chemistry
Keywords Copper(I); tertiary phosphine; luminescence; cluster
Description Depending on the Cu-I halide, ligand to metal ratio, and reaction conditions, complexes with various central CuX clusters can be prepared. A series of reactions of Cu-I halides with P-III containing ligands was carried out in different molar ratios in different solvents, yielding new Cu-I complexes, which were characterized by P-31 NMR and X-ray diffraction. The P-III containing ligands were based on tertiary phosphines carrying at least one organic functional group (e.g. CN, COOH) on aryl substituents. Luminescence in the complexes and its dependence on various conditions (i.e. solvent, temperature, etc.) was studied.

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