Publication details

Identification of Anthocyanins in Red Grape, Plum and Capulin by MALDI-ToF MS

Authors

CASTANEDA-OVANDO Araceli ŠEDO Ondrej HAVEL Josef PACHECO Lourdes ANDRES GALAN-VIDAL Carlos CONTRERAS LOPEZ Elizabeth

Year of publication 2012
Type Article in Periodical
Magazine / Source JOURNAL OF THE MEXICAN CHEMICAL SOCIETY
MU Faculty or unit

Faculty of Science

Citation
Web http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2012000400004
Keywords MALDI-ToF MS; Grapes; Plums; Capulins; Deprotonated Anthocyanins
Description A simple and fast method was developed to identify anthocyanins in red grapes, plums and capulins by MALDI-ToF MS. Three different matrices were used: alpha-CHCA (alpha-cyano-4-hydroxycinnamic acid), THA (2',4',6'-trihydroxyacetophenone) and DHBA (2,5-dihydroxybenzoic acid). Post-Source Decay (PSD) fragment detection allowed studying the structure of compounds detected. Deprotonated anthocyanin species were assigned in capulin ([Cyanidin-3-glucoside-deprotonated] K+ and [Cyanidin-3-rutinoside-deprotonated]K+), due to these compounds also can be ionized in form of potassium adducts combined with a deprotonation.

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