Publication details
Identification of Anthocyanins in Red Grape, Plum and Capulin by MALDI-ToF MS
Authors | |
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Year of publication | 2012 |
Type | Article in Periodical |
Magazine / Source | JOURNAL OF THE MEXICAN CHEMICAL SOCIETY |
MU Faculty or unit | |
Citation | |
Web | http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S1870-249X2012000400004 |
Keywords | MALDI-ToF MS; Grapes; Plums; Capulins; Deprotonated Anthocyanins |
Description | A simple and fast method was developed to identify anthocyanins in red grapes, plums and capulins by MALDI-ToF MS. Three different matrices were used: alpha-CHCA (alpha-cyano-4-hydroxycinnamic acid), THA (2',4',6'-trihydroxyacetophenone) and DHBA (2,5-dihydroxybenzoic acid). Post-Source Decay (PSD) fragment detection allowed studying the structure of compounds detected. Deprotonated anthocyanin species were assigned in capulin ([Cyanidin-3-glucoside-deprotonated] K+ and [Cyanidin-3-rutinoside-deprotonated]K+), due to these compounds also can be ionized in form of potassium adducts combined with a deprotonation. |