Publication details
N-Cyclohexylcyclohexanaminium chloride
| Authors | |
|---|---|
| Year of publication | 2011 |
| Type | Article in Periodical |
| Magazine / Source | Acta Crystallographica Section E: Structure Reports Online |
| MU Faculty or unit | |
| Citation | |
| web | https://doi.org/10.1107/S1600536811000857 |
| Doi | http://dx.doi.org/10.1107/S1600536811000857 |
| Keywords | single-crystal X-ray study; T = 120 K; mean (C–C) = 0.003 angstrom; R factor = 0.025; wR factor = 0.057; data-to-parameter ratio = 9.0 |
| Description | In the title salt, C12H24N+center dot Cl-, both cyclohexyl rings adopt chair conformations and the NH2 unit is situated in the equatorial position with respect to the rings in the cation. The large C-N-C bond angle [117.99 (14)degrees] in the cation is a result of linking two bulky cyclohexyl rings to the N atom. The aminium H atoms are involved in intermolecular N-H center dot center dot center dot Cl hydrogen bonds, forming an infinite zigzag chain parallel to the c axis. The crystal studied was a racemic twin with a twin fraction of 0.28 18). |