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Metal Ionization in Sub-atmospheric Pressure MALDI Interface: A New Tool for Mass Spectrometry of Volatile Organic Compounds
Title in English | Metal Ionization in Sub-atmospheric Pressure MALDI Interface: A?New Tool for Mass Spectrometry of Volatile Organic Compounds |
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Authors | |
Year of publication | 2021 |
Type | Article in Periodical |
Magazine / Source | Analytical Chemistry |
MU Faculty or unit | |
Citation | |
Web | http://pubs.acs.org/doi/10.1021/acs.analchem.1c01124 |
Doi | http://dx.doi.org/10.1021/acs.analchem.1c01124 |
Keywords | analytical methods; mass spectrometry; volatile organic compounds; gold; gas-phase reactions; laser ablation |
Description | A novel approach for the analysis of volatile organic compounds (VOCs) based on chemical ionization by Au+ ions has been proposed. The ionization is carried out in a commercially available dual sub-atmospheric pressure MALDI/ESI interface without any modifications. The Au+ ions are generated by laser ablation of a gold nanolayer with the MALDI laser and VOCs are infused via the ESI capillary. |
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