Publication details

1,3-Dipolar Cycloadditions of Phenanthridinium-Based Azomethine Ylides

Authors

DOSTÁL Jiří POTÁČEK Milan HUMPA Otakar MAREK Jaromír

Year of publication 1994
Type Article in Periodical
Magazine / Source Bulletin des Sociétés Chimiques Belges
MU Faculty or unit

Faculty of Science

Citation
Field Organic chemistry
Keywords Dipolar Cycloadditions; Phenanthridinium; Azomethine Ylides
Description 1,3-Dipolar Cycloadditions; Phenanthridinium; Azomethine Ylides. Azomethine ylides generated from 5-(alkoxycarbonylmethyl)phenanthridinium cations were studied in 1,3-dipolar cycloadditions with dimethyl maleate and dimethyl fumarate as dipolarophiles. The cycloadducts with the pyrrolidino[1,2-f]phenanthridine skeleton easily underwent dehydrogenation. The structure of products was determined by X-ray, NMR and MS.

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