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Publication details
1,3-Dipolar Cycloadditions of Phenanthridinium-Based Azomethine Ylides
Authors | |
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Year of publication | 1994 |
Type | Article in Periodical |
Magazine / Source | Bulletin des Sociétés Chimiques Belges |
MU Faculty or unit | |
Citation | |
Field | Organic chemistry |
Keywords | Dipolar Cycloadditions; Phenanthridinium; Azomethine Ylides |
Description | 1,3-Dipolar Cycloadditions; Phenanthridinium; Azomethine Ylides. Azomethine ylides generated from 5-(alkoxycarbonylmethyl)phenanthridinium cations were studied in 1,3-dipolar cycloadditions with dimethyl maleate and dimethyl fumarate as dipolarophiles. The cycloadducts with the pyrrolidino[1,2-f]phenanthridine skeleton easily underwent dehydrogenation. The structure of products was determined by X-ray, NMR and MS. |