Publication details
The Reaction of P3N3Cl4(NH2)2 with HCl; The Crystal Structure of P3N3Cl5(NH2).
| Title in English | The Reaction of [P3N3Cl4(NH2)2] with [HN(POCl2)2]; the Crystal Structure of a Phosphazenium Salt [P3N3HCl4(NH2)2]+ [N(POCl2)2]-. |
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| Authors | |
| Year of publication | 1997 |
| Type | Article in Periodical |
| Magazine / Source | Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -] |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Keywords | preparation; crystal structure; molecular structure; vibrational spectra |
| Description | P3N3Cl5(NH2) in high purity and good yield can be obtained by the reaction of P3N3Cl4(NH2)2 with gaseous HCl in acetonitrile If diethylether or dichlormethane is used as a solvent, a salt-like compound [P3N3Cl4H(NH2)2+Cl- is formed as a microcrystalline product instead of P3N3Cl5(NH2). The crystal structure of P3N3Cl5(NH2)was determined by X-ray structure analysis. Vibrational spectra and thermic behavior of both P3N3Cl5(NH2)and [P3N3Cl4H(NH2)2+Cl- are also briefly discussed. |
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