Publication details
Quantitative Intermolecular Interactions Analysis and Magnetic Properties of Thiocyanatoiron(II) Complex with Nicotinamide Ligand
| Authors | |
|---|---|
| Year of publication | 2022 |
| Type | Article in Periodical |
| Magazine / Source | Russian Journal of Inorganic Chemistry |
| MU Faculty or unit | |
| Citation | |
| Web | https://link.springer.com/article/10.1134/S0036023622100357 |
| Doi | http://dx.doi.org/10.1134/S0036023622100357 |
| Keywords | crystal structure; hydrogen bonding; Hirshfeld surface analysis; antiferromagnetsm; ferromagnetism |
| Description | A new [Fe-(mu-NCS)(2)(H2O)(2)(nicotinamide)(2)] complex was synthesized and characterized. The structure is characterized by IR spectroscopy, TGA, single crystal X-ray diffraction and magnetic measurements. Further, the quantitative intermolecular interactions analysis and interactions energy calculation has been also carried out through Hirshfeld surface analysis. The X-ray structure revealed that complex is comprised of one unit in which iron atoms are connected through two nitrogen atoms from nicotinamide molecule, two nitrogens from thiocyanate ligand and two oxygen from water molecules. |