Publication details

Stereoselective 1,3-Dipolar Cycloaddition Reactions of gamma-Substituted alpha-Methylene-gamma-lactones

Authors

MAZAL Ctibor MELŠA Petr

Year of publication 2000
Type Article in Proceedings
Conference 8th Blue Danube Symposium on Heterocyclic Chemistry, Program, Abstract of Papers, List of Participants
MU Faculty or unit

Faculty of Science

Citation
Field Organic chemistry
Description Diatereoselectivity of 1,3-dipolar cycloaddition reactions to alpha-methylene-gamma-lactone dipolaropholes was controlled by placing a bulky substituent (OBO) into gamma-position of lactone ring. The enantiomerically pure dipolarophiles were prepared in good yield from easy accessible L-glutamic acid.
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