Publication details

Influence of N-Substituents of Carbamoyl-stabilized Azomethine Ylides in 1,3-Dipolar Cycloadditions

Authors

POSPÍŠIL Jiří TRÁVNÍČEK Martin POTÁČEK Milan

Year of publication 2002
Type Article in Periodical
Magazine / Source ARKIVOC
MU Faculty or unit

Faculty of Science

Citation
Web http://www.arkat-usa.org/ark/journal/Volume2/Part3/Sauter/FS173F/FS173F.pdf
Field Organic chemistry
Keywords 1;3-Dipolar cycloaddition; azomethine ylides; N-substituted 2-bromoacetamides; phenanthridinium salts; pyrrolidino[1;2-f]phenanthridines
Description Upon treatment with base N-substituted carbamoylmethylphenanthridinium salts were converted into azomethine ylides. These intermediates were intercepted with symmetrically substituted dipolarophiles, and the stereochemistry of the cycloadducts has been found to be dependent on the substitution at the amide nitrogen atom.
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