Publication details
Influence of N-Substituents of Carbamoyl-stabilized Azomethine Ylides in 1,3-Dipolar Cycloadditions
| Authors | |
|---|---|
| Year of publication | 2002 |
| Type | Article in Periodical |
| Magazine / Source | ARKIVOC |
| MU Faculty or unit | |
| Citation | |
| web | http://www.arkat-usa.org/ark/journal/Volume2/Part3/Sauter/FS173F/FS173F.pdf |
| Field | Organic chemistry |
| Keywords | 1;3-Dipolar cycloaddition; azomethine ylides; N-substituted 2-bromoacetamides; phenanthridinium salts; pyrrolidino[1;2-f]phenanthridines |
| Description | Upon treatment with base N-substituted carbamoylmethylphenanthridinium salts were converted into azomethine ylides. These intermediates were intercepted with symmetrically substituted dipolarophiles, and the stereochemistry of the cycloadducts has been found to be dependent on the substitution at the amide nitrogen atom. |
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