Publication details
Nickel(II) hexamethyleneiminedithiocarbamate complexes with triphenylphosphine or tributylphosphine
| Authors | |
|---|---|
| Year of publication | 2003 |
| Type | Article in Periodical |
| Magazine / Source | Transition Metal Chemistry |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Description | A series of square-planar nickel(II) hexamethylenedithiocarbamate complexes with heterogeneous coordination spheres of composition [NiX(hmidtc)Y] . nCHCl(3) [X = Cl, Br, I or NCS; hmi = C6H12, dtc = S2CN-; Y = PPh3 or PBu3, n = 0; 1] have been synthesized and characterized by elemental analyses, i.r. and u.v.-v.i.s. spectroscopy, magnetochemical and conductivity measurements, and by thermal analysis. X-ray structures of [NiCl(hmidtc)(PPh3)] .CHCl3 and [NiBr(hmidtc)(PPh3)].CHCl3 have been determined. |