Publication details
Tris(1,10-phenanthroline)sodium 2,4,6-trimercapto-1,3,5-triazin-1-ide
| Authors | |
|---|---|
| Year of publication | 2003 |
| Type | Article in Periodical |
| Magazine / Source | Acta Crystallographica Section C: Crystal Structure |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Keywords | Hydrogen bonding; Trithiocyanuric acid |
| Description | The title compound, [Na(C12H8N2)3](C3H2N3S3), contains an Na+ centre which is ionicly bonded to three 1,10-phenanthroline (phen) ligands and one trithiocyanurate(1-) (ttcH2) anion. In the crystal structure, the anions are linked via hydrogen bonds to form linear chains. The S and H atoms of the ttcH2 anion participate in intermolecular N-HS hydrogen bonding, with NS distances of 3.298 (2) and 3.336 (2) A. The phen ligands are almost parallel, with dihedral angles of 3.92 (5), 11.75 (5) and 15.45 (5) deg; moreover, they are nearly perpendicular to the ttcH2 chains, with angles of 81.94 (7), 85.86 (7) and 85.96 (7)deg. |
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