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Publication details
Laser ablation synthesis and TOF mass spectrometric identification of tellurium, sulfur and mixed tellurium-sulfur clusters
Authors | |
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Year of publication | 2003 |
Type | Article in Periodical |
Magazine / Source | Polyhedron |
MU Faculty or unit | |
Citation | |
Field | Inorganic chemistry |
Keywords | tellurium;sulfur;clusters;laser ablation synthesis;mass spectrometry;post-source decay |
Description | It was found that laser ablation of a mixture of elemental tellurium and sulfur is a possible way for synthesis of heteroatomic clusters. Four new cluster families with the composition TeSn(n = 1-14), Te2Sn(n = 1-10), Te3Sn(n = 1-6) and Te4Sn(n = 1-2) were produced with a negative or positive charge. Simultaneously, the formation of Te-n(+) and Te-n(-) (n = 1-6), S-n(+) (n = 1-11) and S-n(-) (n = 1-15) clusters was observed. |
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