Publication details

SYNTHESIS OF A NOVEL 4H-BENZO[1.2.4]DITHIAZINE SYSTEM AND STUDIES OF ITS ELECTROCHEMICAL BEHAVIOUR

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Authors

PAZDERA Pavel ŠIMBERA Jan MUZIKANTOVÁ Vladimíra TRNKOVÁ Libuše

Year of publication 2003
Type Article in Proceedings
Conference Proceedings of ECSOC-7, The Seventh International Electronic Conference on Synthetic Organic Chemistry, http://www.mdpi.org/ecsoc-7.htm, September 1-30, 2003. Editors: Julio A. Seijas, De-Chun Ji and Shu-Kun Lin. CD-ROM edition
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Faculty of Science

Citation PAZDERA, Pavel, Jan ŠIMBERA, Vladimíra MUZIKANTOVÁ and Libuše TRNKOVÁ. SYNTHESIS OF A NOVEL 4H-BENZO[1.2.4]DITHIAZINE SYSTEM AND STUDIES OF ITS ELECTROCHEMICAL BEHAVIOUR. In Proceedings of ECSOC-7, The Seventh International Electronic Conference on Synthetic Organic Chemistry, http://www.mdpi.org/ecsoc-7.htm, September 1-30, 2003. Editors: Julio A. Seijas, De-Chun Ji and Shu-Kun Lin. CD-ROM edition. 1st ed. Basel: Publisher MDPI, Matthaeusstrasse 11, CH-4057 Basel, Switzerland, 2003, p. 24-30. ISBN 3-906980-13-8.
web http://www.mdpi.org/ecsoc-7.htm
Field Organic chemistry
Keywords 4H-BENZO[1.2.4]DITHIAZINE; redox ring opening-closure; cyclic voltametry
Description Compounds containing the chalcogen-chalcogen bond (chalkogen can be sulphur and/or selenium) in molecules could be potential scavenger for free radicals in organisms, because the bond chalcogen-chalcogen may be liable to the reversible redox bond-opening and bond-closure. Now we found a facile method for preparation of the new benzo[1,2,4]dithiazine skeleton containig -S-S- moiety into molecule. Electrochemical studies show the reversible redox ring-opening and ring-closure on S-S bond of skeleton.
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