Dichlorotetrakis(tetrahydrofuran)aluminium trichloroethylaluminate

• Authors: SLUKA Radek; NEČAS Marek; ŠINDELÁŘ Pavel
• Year of publication: 2004
• Type: Article in Periodical
• Magazine / Source: Acta Crystallographica Section E: Structure Reports Online
• MU Faculty or unit: Faculty of Science
• Field: Inorganic chemistry
• Keywords: ALUMINUM TRICHLORIDE; TETRAHYDROFURAN; CRYSTAL; COMPLEXES
• Description: The title compound, [AlCl2(C4H8O)(4)][AlCl3(C2H5)], was prepared by the unsymmetrical cleavage reaction of the EtAlCl2 dimer with tetrahydrofuran (THF). The [AlCl2(THF)(4)](+) cation forms an approximately regular octahedron, and the [AlCl3Et](-) anion is tetrahedral.

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