Publication details

Thermodynamic assessment of the Hg-Tl system

Authors

GIERLOTKA W. SOPOUŠEK Jiří FITZNER K.

Year of publication 2006
Type Article in Periodical
Magazine / Source CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
MU Faculty or unit

Faculty of Science

Citation
Field Physical chemistry and theoretical chemistry
Keywords Assessment; amalgam; liquid
Description The phase diagram and thermodynamic properties of the Hg-Tl binary system were modeled by means of the CALPHAD method, using experimental information as reported in the literature. A good agreement was observed between our calculated data and the existing experimental data. Also, an interesting result was established about the dependence of entropy and enthalpy of mixing functions on temperature, and at the same time, on practically ideal activity vs. concentration. The Gamma phase was described for the first time using the substitional RKMP model.

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