Publication details
(mu(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa N-3,N ',N '')copper(II)] tris(perchlorate)
| Authors | |
|---|---|
| Year of publication | 2007 |
| Type | Article in Periodical |
| Magazine / Source | Acta Crystallographica Section E: Structure Reports Online |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Keywords | CRYSTAL |
| Description | In the title compound, [Cu-3(C9H23N3)(3)(C3N3S3)](ClO4)(3), the three Cu-II centres, related by the body-diagonal threefold rotation symmetry along [ 111], are bridged by a trithiocyanurate( 3 -) anion ( ttc), with each centre having a considerably distorted trigonal - bipyramidal geometry and bonded to three N atoms of a tridentate N, N, N', N '', N ''-pentamethyldiethylenetriamine ligand, and one S and one N atoms of the ttc ligand. The secondary structure is stabilized by a variety of weak hydrogen bonds of the type C - H center dot center dot center dot O ( H center dot center dot center dot A < 2.7 angstrom) connecting the cation and perchlorate anions. |
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