Fluorinated photoremovable protecting groups: the influence of fluoro substituents on the photo-Favorskii rearrangement

• Authors: STENSRUD Kenneth F.; HEGER Dominik; ŠEBEJ Peter; WIRZ Jakob; GIVENS Richard S.
• Year of publication: 2008
• Type: Article in Periodical
• Magazine / Source: Photochemical & Photobiological Sciences
• MU Faculty or unit: Faculty of Science
• Web: http://www.rsc.org/Publishing/Journals/PP/article.asp?doi=b719367j
• Field: Nuclear and quantum chemistry, photochemistry
• Keywords: Photoremovable Protecting Group; p-Hydroxyphenacyl Protecting Group; Fluorinated Photoremovable Protecting Groups; Laser Flash Photolysis
• Description: To further explore the nature of the photo-Favorskii rearrangement and its commitment to substrate photorelease from p-hydroxyphenacyl (pHP), an array of ten new fluorinated pHP gama-aminobutyric acid (GABA) derivatives was synthesized and photolyzed.

Related projects

• Proteins in metabolism and interaction of organisms with the environment