Publication details

ELECTROANALYSIS OF ADENINE DERIVATES AT GLASSY CARBON ELECTRODE USING FLOW INJECTION ANALYSIS AND LIQUID CHROMATOGRAPHY

Authors

ZÍTKA Ondřej DUŠA Filip HÚSKA Dalibor ADAM Vojtěch TRNKOVÁ Libuše JELEN František KIZEK René

Year of publication 2008
Type Article in Proceedings
Conference Chemické listy
MU Faculty or unit

Faculty of Science

Citation
Field Electrochemistry
Keywords adenine; coulometry; glassy carbon electrode
Description In the present work we focused on study of basic behaviour of adenine and its derivates (adenosine, S-adenosyl-L-methionin, 6-benzyl aminopurine, adenosine monophosphate) in flow system. To measure the target molecules we employed flow injection analysis coupled with electrochemical (CoulochemIII) and UV-VIS detector. The most suitable pH value for determination of the target molecules was 2 and the optimal working electrode potential was 900 mV. Under the optimized conditions we attempted to determine all target molecules simultaneously. The analysis took 7 minutes with micromolar detection limit.

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