Publication details
(1-Adamantyl){4-[(2-chloro-9-isopropyl-9H-purin-6-yl)aminomethyl]phenyl}-methanone trichloromethane solvate
| Authors | |
|---|---|
| Year of publication | 2009 |
| Type | Article in Periodical |
| Magazine / Source | Acta Crystallographica Section E: Structure Reports Online |
| MU Faculty or unit | |
| Citation | |
| Web | http://journals.iucr.org/e/issues/2009/06/00/bi2361/index.html |
| Field | Organic chemistry |
| Keywords | PURINES |
| Description | In the title compound, C26H30ClN5O center dot CHCl3, the purine molecule consists of essentially planar benzene and purine ring systems [maximum deviation 0.010 (4) angstrom for both ring systems] forming a dihedral angle of 85.52 (9)degrees. Intermolecular N-H center dot center dot center dot N hydrogen bonds link adjacent molecules into centrosymmetric dimers. The structure also contains intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot N interactions. The benzene rings form offset face-to-face pi-pi stacking interactions with an interplanar distance of 3.541 (4) angstrom and a centroid-to-centroid distance of 4.022 (4) angstrom. |