Publication details

Adsorption and 2D condensation of cytosine derivatives

Authors

FOJT Lukáš VETTERL Vladimír DONEUX Thomas

Year of publication 2009
Type Article in Proceedings
Conference XXth International Symposium on Bioelectrochemistry and Bioenergetics, Sibiu, Romania, 10. – 14.5.2009, Book of Abstracts
MU Faculty or unit

Faculty of Medicine

Citation
Field Biophysics
Keywords Cytosine derivatives; 2D condensation; self-assembled monolayers
Description Purine and pyrimidine derivatives occurring in nucleic acids posses an extraordinary high ability of self association at the electrode surface and can form there by a two-dimensional (2D) condensation a monomolecular compact film (self assembled monolayer SAM). The effects of halogen and methyl substituents on the 2D condensation of cytosine were studied. For the first time the 2D condensation of 5-fuorocytosine at the hanging mercury electrode was observed. The formation of 2D condensed layers of different cytosine derivatives at the Au(111) single crystal electrode we have observed as well.
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