Publication details
Unexpected Heterocyclic Products from Cycloaddition Reactions of Nonsymmetrical Allenyl Aldoketazines with Substituted Alkynes
| Authors | |
|---|---|
| Year of publication | 2011 |
| Type | Article in Periodical |
| Magazine / Source | European Journal of Organic Chemistry |
| MU Faculty or unit | |
| Citation | |
| web | http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201001044/abstract |
| Doi | http://dx.doi.org/10.1002/ejoc.201001044 |
| Field | Organic chemistry |
| Keywords | alkynes; allenes; nitrogen heterocycles; azines; cycloaddition; cyclotrimerization |
| Description | Criss-cross cycloaddition reactions of non-symmetrical aldoketazines with alkynes depending on various substitution afforded three types of heterocyclic products. Diastereoselectivity and regioselectivity were observed and reaction pathways and mechanisms are discussed supported by X-ray analyses. |
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