Publication details

Experimental study and thermodynamic remodeling of the Bi-Cu-Ni system

Authors

MARKOVIC Bronislav ŽIVKOVIC Dragana VŘEŠŤÁL Jan MANASIJEVIC Dragan MINIC Dusko STAJIC-TROSIC Jasna TODOROVIC Radisa

Year of publication 2010
Type Article in Periodical
Magazine / Source CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
MU Faculty or unit

Faculty of Science

Citation
Field Thermodynamics
Keywords Phase equilibria Thermodynamic modeling Thermal analysis Bi-Cu-Ni system
Description Phase equilibria in the Bi/Cu/Ni ternary system have been studied using DTA as well as by using the calculation of phase diagram (CALPHAD) method. Literature experimental phase equilibria data and DTA results from this study were used for thermodynamic modeling of the Bi/Cu/Ni ternary system. Isothermal sections at 300, 400, and 500 oC, vertical sections from bismuth corner with molar ratio Cu:Ni=1/3, 1/1 and 3/1 and vertical section at 40 at.% Cu were calculated and compared with corresponding experimental results. Reasonable agreement between calculation and experimental data was observed in all cases.
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