Publication details
Synthesis of Organotitanium(IV) Fluoride Phosphates and the Crystal Structure of [(C5Me4Et)TiF(m-F){m-O2P(OSiMe3)2}]2
| Authors | |
|---|---|
| Year of publication | 2012 |
| Type | Article in Periodical |
| Magazine / Source | Acta Chimica Slovenica |
| MU Faculty or unit | |
| Citation | |
| web | http://acta.chem-soc.si/59/59-1-203.pdf |
| Field | Inorganic chemistry |
| Keywords | titanium; fluoride; phosphate; X-ray structure |
| Attached files | |
| Description | The complexes [(C5Me4R)TiF(m-F){m-O2P(OSiMe3)2}]2 [R = Me (1), Et (2)] were prepared from [(C5Me4R)TiF3]2, (R = Me, Et) and OP(OSiMe3)3. The molecular structure of 2 has been determined by single-crystal X-ray diffraction analysis. An eight-membered Ti2O4P2 metallacycle bridged by two fluorine ligands between two titanium centers is observed. |
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