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Synthesis of Heteroleptic Tin N,O-B-Heteroarylaketonate Complexes, Their Properties and Reactivity
Název česky | Syntézy heteroleptických N,O-B-Heteroarylaketonátových komplexů cínu, jejich vlastnosti a reaktivita |
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Autoři | |
Rok publikování | 2015 |
Druh | Konferenční abstrakty |
Fakulta / Pracoviště MU | |
Citace | |
Popis | In our work, we synthetized two novel heteroleptic alkoxidic compounds, containing tin (IV) coordinated with N,O–B–heteroarylalkenolato ligands, Sn(4,5–Me–OxCHCOCF3)2(OtBu)2 and Sn(2–PyCHCOCF3)2(OtBu)2: Those compounds were fully structurally characterized and their properties and reactivity towards water and fluorination agents were investigated. Obtained results were compared with homoleptic tin (II) N,O–B–heteroarylalkenolato complexes already published in literature, Sn(4,5–Me–OxCHCOCF3)2 and Sn(2–PyCHCOCF3)2. |
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