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Application of a new HPLC-ICP-MS method for simultaneous determination of Al3+ and aluminium fluoride complexes
Autoři | |
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Rok publikování | 2015 |
Druh | Článek v odborném periodiku |
Časopis / Zdroj | HELIYON |
Fakulta / Pracoviště MU | |
Citace | |
www | https://doi.org/10.1016/j.heliyon.2015.e00035 |
Doi | http://dx.doi.org/10.1016/j.heliyon..2015.e00035 |
Klíčová slova | Earth sciences; Chemistry; Analytical chemistry applications; Analytical chemistry; HPLC |
Popis | The paper presents the new HPLC-ICP-MS method used for conducting speciation analysis of aluminum as free Al3+ and aluminum fluoride complexes during one analysis. In the study, 5% HNO3 was used as a derivative reagent in order to minimize the possibility of clogging the torch in ICP-MS. Using the new HPLC-ICP-MS method, speciation analysis of aluminum and aluminum fluoride complexes was conducted on the basis of model solutions and real samples (soil-water extracts and groundwater samples). The analysis in the presented analytical system lasts only 4 min. |