Informace o publikaci

Amgaite, Tl23+Te6+O6, a New Mineral from the Khokhoyskoe Gold Deposit, Eastern Siberia, Russia

Autoři	KASATKIN Anatoly V. ANISIMOVA Galina S. NESTOLA Fabrizio PLÁŠIL Jakub SEJKORA Jiří ŠKODA Radek SOKOLOV Evgeniy P. KONDRATIEVA Larisa A. KARDASHEVSKAIA Veronika N.
Rok publikování	2022
Druh	Článek v odborném periodiku
Časopis / Zdroj	Minerals
Fakulta / Pracoviště MU	Přírodovědecká fakulta
Citace
www	https://www.mdpi.com/2075-163X/12/9/1064
Doi	http://dx.doi.org/10.3390/min12091064
Klíčová slova	amgaite; new mineral; Khokhoyskoe gold deposit; Amga river; Raman spectroscopy; chemistry; synthetic Tl23+Te6+O6; trivalent thallium
Popis	The new mineral amgaite was discovered at the Khokhoyskoe gold deposit, 120 km W of Aldan town, Aldanskiy District, Sakha Republic (Yakutia), Eastern Siberia, Russia. Amgaite forms fine-grained colloform aggregates up to 0.05 mm across, and is often intimately intergrown with avicennite, unidentified carbonates and antimonates of Tl. Other associated minerals include gold, silver, acanthite, arsenopyrite, pyrite, berthierite, chalcocite, weissbergite, chlorargyrite, calcite, quartz, goethite etc. Amgaite is dark reddish brown to black. It has submetallic luster, black streak, brittle tenacity and conchoidal fracture. Its density calculated from the empirical formula and powder XRD data is 8.358 g/cm3. Its Mohs’ hardness is ca. 1.5–2. Optically, amgaite is uniaxial. In reflected light, it is gray with a bluish shade, very weakly anisotropic with rare brownish red internal reflections. Reflectance values for the four COM wavelengths [Rmin, Rmax (%)(? in nm)] are: 13.5, 14.2 (470); 12.7, 13.2 (546); 12.3, 12.7 (589); and 11.7, 12.3 (650). The Raman spectrum shows bands of Te–O and Tl–O bonds and confirms the absence in amgaite of H2O, OH–, CO32– groups and B–O bonds. The chemical composition is (electron microprobe, wt.%): MgO 0.43, CaO 1.62, Fe2O3 0.36, Tl2O3 66.27, Sb2O5 3.48, TeO3 27.31, total 99.47. The empirical formula based on 6 O apfu is Tl3+1.74Ca0.17Mg0.06Fe3+0.03Te6+0.93Sb5+0.13O6. Amgaite is trigonal, space group P321; unit-cell parameters are as follows: a = 9.0600(9), c = 4.9913(11) A, V = 354.82(8) A3, Z = 3. The strongest lines of the powder X-ray diffraction pattern [dobs, A (I, %) (hkl)] are as follows: 3.352 (100) (111), 3.063 (15) (201), 2.619 (49) (300), 2.065 (18) (221), 1.804 (28) (302), 1.697 (8) (321), 1.625 (9) (411). The crystal structure of amgaite is the same as of synthetic Tl3+2Te6+O6. The new mineral is named after the Amga River, the basin of which hosts the type locality, Khokhoyskoe occurrence. The type material is deposited in the collections of the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia, with the registration number 5773/1.