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Polybrominated diphenyl ether contamination in sediments from rivers in the western Niger Delta of Nigeria

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IWEGBUE Chukwujindu M. A. OSHENYEN Ejonafuvwe V. PERETIEMO-CLARKE Beatrice O. OLISAH Chijioke NWAJEI Godwin E. MARTINCIGH Bice S.

Rok publikování 2024
Druh Článek v odborném periodiku
Časopis / Zdroj Marine Pollution Bulletin
Fakulta / Pracoviště MU

Přírodovědecká fakulta

Citace
www https://www.sciencedirect.com/science/article/pii/S0025326X24000171?via%3Dihub
Doi http://dx.doi.org/10.1016/j.marpolbul.2024.116040
Klíčová slova Polybrominated diphenyl ethers; Sediments; River systems; Niger Delta
Popis This study investigated the concentrations of 39 polybrominated diphenyl ether (PBDE) congeners in sediments from three rivers in the western Niger Delta of Nigeria that have been affected by pollution from urbanization and industrial activities. The Sigma 39 PBDE concentrations in sediments from these rivers ranged from 0.29 to 95.5, 5.15 to 121, and 0.73 to 66.1 ng g -1 for the Afiesere (AR), Edor (ER), and Okpare Rivers (OR), respectively. The homologue distribution patterns indicated the prominence of tetra- and penta-BDE congeners in sediments from these rivers. The ecological risk assessment results showed that the penta-BDEs were the primary source of risk to sediment -dwelling organisms in these rivers. However, the human health risk assessment indicated negligible risks for exposure of both adults and children to PBDEs in these sediments. The source apportionment suggests that the PBDE contamination in these river sediments was derived from long-distance migration, debromination of highly brominated congeners, and commercial penta-BDEs. These results reflect the use of penta-BDE formulations in this region rather than octa- and deca-BDE formulations.

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