Informace o publikaci
Bis(4-dimethylaminopyridinium) 1,2-difluorodiphosphate
| Autoři | |
|---|---|
| Rok publikování | 2003 |
| Druh | Článek v odborném periodiku |
| Časopis / Zdroj | Acta Crystallographica Section E: Structure Reports Online |
| Fakulta / Pracoviště MU | |
| Citace | |
| Obor | Anorganická chemie |
| Klíčová slova | single-crystal X-ray study; T=120 K; mean sigma(C-C)=0.005 angstrom; R factor=0.045; wR factor=0.142; data-to-parameter ratio=12.9 |
| Popis | Bis(4-dimethylaminopyridinium) 1,2-difluorodiphosphate, [DMAPH]2[P2O5F2], belongs to the class of catena-difluoropolyphosphates of general formula [PnO3n-1F2]n- (n=2,3,...), and is the second representative of this series characterized by single-crystal X-ray diffraction. Compared to K2[P2O5F2] the anion adopts a different conformation enforced by its N-H...O bridging to the cation. |
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