Informace o publikaci
[N,N'-Bis(3-aminopropyl)ethylenediamine-kappa4N,N',N'',N'''](trithiocyanurato-kappa2N,S)zinc(II) ethanol solvate
| Autoři | |
|---|---|
| Rok publikování | 2003 |
| Druh | Článek v odborném periodiku |
| Časopis / Zdroj | Acta Crystallographica Section C: Crystal Structure |
| Fakulta / Pracoviště MU | |
| Citace | |
| Obor | Anorganická chemie |
| Klíčová slova | crystal structure; zinc(II); trithiocyanuric acid |
| Popis | In the crystal structure of the title compound, [N,N'-bis(3-aminopropyl)ethylenediamine-kappa4N,N',N'',N'''][1,3,5-triazine-2,4,6(1H,3H,5H)-trithionato(2-)-kappa2N,S]zinc(II) ethanol solvate, [Zn(C8H22N4)2(C3HN3S3)].C2H6O, the ZnII atom is octahedrally coordinated by four N atoms [Zn-N = 2.104 (2)-2.203 (2) A] of a tetradentate N-donor N,N'-bis(3-aminopropyl)ethylenediamine (bapen) ligand and by two S and N atoms [Zn-S = 2.5700 (7) A and Zn-N = 2.313 (2) A] of a trithiocyanurate(2-) (ttcH2-) dianion bonded as a bidentate ligand in a cis configuration. The crystal structure of the compound is stabilized by a network of hydrogen bonds. |
| Související projekty: |