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Informace o publikaci
Elimination Voltammetry of Miniaturized Mercury Drop Electrodes
Autoři | |
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Rok publikování | 2010 |
Druh | Článek v odborném periodiku |
Časopis / Zdroj | Electroanalysis |
Fakulta / Pracoviště MU | |
Citace | |
Obor | Fyzikální chemie a teoretická chemie |
Klíčová slova | Elimination voltammetry with linear scan (EVLS); Linear sweep voltammetry (LSV); Mini-drop electrodes; Cottrell equation; Spherical diffusion; Voltammetry; Hydrogen evolution |
Popis | Elimination voltammetry with linear scan (EVLS) in connection with renewed mini- drop mercury electrodes provides valuable information about the character and kinetics of processes at electrode/electrolyte interfaces. Based on the experiment related to the hydrogen evolution, it is presented that the EVLS is more sensitive than other voltammetric methods. Using miniaturized mercury electrodes, the EVLS is capable of detecting the effect of spherical diffusion associated with both the scan rates and the size of an electrode drop. |
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