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Direct alkylation of gold surface

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KALETOVÁ Eva KOHUTOVÁ Anna SI Zhenjun KALETA Jiří SCHOLZ Frank HAJDUCH Jan POSPÍŠIL Lubomír VON WROCHEM Florian BASTL Zdeněk MICHL Josef

Rok publikování 2012
Druh Konferenční abstrakty
Fakulta / Pracoviště MU

Přírodovědecká fakulta

Citace
Popis We report methods for ambient solution coating of a gold surface with a self-limiting monolayer containing alkyl chains attached by one or more C-Au bonds, and no other elements. The alkyl transfer agents are alkyl derivatives of metals such as Sn, Hg, Ge, and others. This is a generalization of our previous finding that under ambient conditions solutions of alkylated stannanes deposit alkyl-containing monolayers on gold surface, and is in accord with break-junction conductivity measurements on single molecules attached to gold through carbon by transfer from trimethylstannyl derivatives.

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