Project information
New Nonaqueous Routes to Phosphate, Silicate, Hybrid, and Oxide Materials
- Project Identification
- GA203/01/1533
- Project Period
- 1/2001 - 1/2003
- Investor / Pogramme / Project type
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Czech Science Foundation
- Standard Projects
- MU Faculty or unit
- Faculty of Science
Study of new nonaqueous methods for the preparation of metallophosphates based on dealkylamination reactions of metal amides with phosphoric acid triesters. Elucidation of the reaction mechanism and optimizing crystallization conditions for the formation of microporous materials using solvents with bulky molecules as templates. Preparation of bimetallic phosphates by reacting mixtures of metal amides with phosphoric acid triesters. Study of the properties of amorphous A1P04 phases. Reactivity studies of the cubic metallophosphonates and metallosiloxanes with protic reagents. Influence of the acidity and steric properties of these reagents on the nature of products. Reactions of bifunctional alcohols and carboxylic acids with metallophosphonates and met allosiloxanes to form cross-linked hybrid materials possessing microporosity. Development of nonaqueous nonhydrolytic sol-gel methods for the preparation of mixed metal oxides with homogeneous mixing of the components at the molecular level based on the
Publications
Total number of publications: 31
2005
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Processing and characterization of sol-gel fabricated mixed metal aluminates
Ceramics International, year: 2005, volume: 31, edition: 8
2004
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Chemical Reactivity of Alumazene
Phosphorus, Sulfur, and Silicon and the Related Elements, year: 2004, volume: 179, edition: 4-5
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Optimalizace přípravy mezostrukturního hlinitého materiálu
Chemické listy, 56. sjezd chemických společností, year: 2004
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Polyhedral Metallophosphonates and silicates: Synthesis, Functionalization, and Transformations
Phosphorus, Sulfur, and Silicon and the Related Elements, year: 2004, volume: 179, edition: 4-5
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Preparation of Monomeric LAl(NH2)2 The First Main-Group Metal Diamide Containing Two Terminal NH2 Groups in the Presence of a N-heterocyclic Carbene as HCl Acceptor
Angewandte Chemie International Edition, year: 2004, volume: 43, edition: 16
2003
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Alumazene - Inorganic Benzene Analog
Inorganic Experiments, J. D. Woollins, Ed., edition: Vyd. 2, year: 2003, number of pages: 3 s.
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DEALKYLSILYLAČNÍ A ADIČNÍ REAKCE ALUMAZENU
Chemické listy, year: 2003
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Chemical Reactivity of Alumazene
10th International Symposium on Inorganic Ring Systems IRISX - O27, year: 2003
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Mezoporézní metalofosfáty přechodných kovů
Juniormat 4th International Conference, year: 2003
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NEHYDROLYTICKÉ METODY PŘÍPRAVY HLINITOFOSFOREČNANŮ
Chemické listy, year: 2003