Project information
New Nonaqueous Routes to Phosphate, Silicate, Hybrid, and Oxide Materials
- Project Identification
- GA203/01/1533
- Project Period
- 1/2001 - 1/2003
- Investor / Pogramme / Project type
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Czech Science Foundation
- Standard Projects
- MU Faculty or unit
- Faculty of Science
Study of new nonaqueous methods for the preparation of metallophosphates based on dealkylamination reactions of metal amides with phosphoric acid triesters. Elucidation of the reaction mechanism and optimizing crystallization conditions for the formation of microporous materials using solvents with bulky molecules as templates. Preparation of bimetallic phosphates by reacting mixtures of metal amides with phosphoric acid triesters. Study of the properties of amorphous A1P04 phases. Reactivity studies of the cubic metallophosphonates and metallosiloxanes with protic reagents. Influence of the acidity and steric properties of these reagents on the nature of products. Reactions of bifunctional alcohols and carboxylic acids with metallophosphonates and met allosiloxanes to form cross-linked hybrid materials possessing microporosity. Development of nonaqueous nonhydrolytic sol-gel methods for the preparation of mixed metal oxides with homogeneous mixing of the components at the molecular level based on the
Publications
Total number of publications: 31
2003
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OPTIMALIZACE PŘÍPRAVY MOLEKULÁRNÍCH KUBICKÝCH HLINITOFOSFONÁTŮ
Chemické listy, year: 2003
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Organoaluminum fluorides
Journal of Fluorine Chemistry, year: 2003, volume: 122, edition: 2
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Polyhedral Metallophosphonates and silicates: Synthesis, Functionalization, and Transformations
10th International Symposium on Inorganic Ring Systems IRISX - P10, year: 2003
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Preparation of Mesoporous Metallophopshate Materials
Euregionale 2003 Book of Abstracts, year: 2003
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Preparation of Metallosilicate and Metallophosphate Compounds
Euregionale 2003 Book of Abstracts, year: 2003
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STUDIUM FÁZOVÝCH PŘEMĚN MEZOPORÉZNÍCH METALOFOSFÁTŮ
Chemické listy, year: 2003
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Supramolecular solid-state architectures constructed from 4,4-bipyridine-N,N-dioxide and dicyanamido tectons. Synthesis and crystal structures of [M(bpno)2{N(CN)2}2(H2O)2]
Polyhedron, year: 2003, volume: 22, edition: 5
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Synthesis and X-ray Crystal Structure of [(THF)Zn(O2(OH)SiR)]4 (R = (2,6-i-Pr2C6H3)N(SiMe3)): Enroute to Larger Aggregates
Inorg. Chem., year: 2003, volume: 42, edition: 4
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VYUŽITÍ SILANOLŮ K PŘÍPRAVĚ MOLEKULÁRNÍCH METALOSILIKÁTOVÝCH SLOUČENIN
Chemické listy, year: 2003
2002
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Adamantane-Like Aluminum Amide-Phosphate from Alumazene
Inorg. Chem., year: 2002, volume: 41, edition: 25