Publication details
Lanthanide coordination polymers with bis(diphenylphosphoryl)bicyclo[1.1.1]pentane
| Authors | |
|---|---|
| Year of publication | 2013 |
| Type | Article in Periodical |
| Magazine / Source | Polyhedron |
| MU Faculty or unit | |
| Citation | |
| web | http://dx.doi.org/10.1016/j.poly.2013.06.026 |
| Doi | http://dx.doi.org/10.1016/j.poly.2013.06.026 |
| Field | Inorganic chemistry |
| Keywords | Bicyclopentanes;Lanthanides;Coordination polymers;X-ray crystallography |
| Description | The reaction of 1,3-bis(diphenylphosphoryl)bicyclo[1.1.1]pentane (1) with lanthanide nitrates provided a series of layered network coordination polymers Ln(1)1.5(NO3)3 (Ln = Ce, Pr, Nd, Eu, Tb, Er, Yb, Lu). Crystal structures of all members of the series were determined by single crystal X-ray diffraction and were found isostructural. The compounds were studied by IR spectroscopy, luminescence spectroscopy, thermal analysis (TG/DSC) and powder X-ray diffraction (PXRD) techniques. |
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