Project information
Synthesis and properties of inorganic-organic polymeric materials
- Project Identification
- GA203/08/1111
- Project Period
- 1/2008 - 12/2010
- Investor / Pogramme / Project type
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Czech Science Foundation
- Standard Projects
- MU Faculty or unit
- Faculty of Science
- Keywords
- polymeric materials, metallophosphates, metallophosphonates, coordination polymers, porosity, luminescence
The project is aimed at the synthesis of new inorganic-organic polymeric materials and studies of their properties. The syntheses will start from organic derivatives of phosphoric and phosphonic acids, and tertiaary phosphine oxides,, reacting with metal salts and oxides, and from the more complex molecular building units. By hydrothermal and solvothermal methods, hydrolytic and nonhydrolytic condensations and self-assembly driven processes, the precursors will form layered and 3D-framework organic-inorganic hybrid materials and coordination polymers. Their compositions, structures, and physicochemical properties will be studied. The structures will be determined by X-ray diffraction and NMR spectroscopy methods, porosity will be examined by adsorption isotherms of gases, and optical properties will be investigated by time-resolved and steady-state luminescence spectroscopies. The results will serve as a feedback for the modification of starting organic ligands and other molecular precursors in the search for optimal pore characteristics and optical properties of the studied materials.
Publications
Total number of publications: 16
2013
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Lanthanide coordination polymers with bis(diphenylphosphoryl)bicyclo[1.1.1]pentane
Polyhedron, year: 2013, volume: 62, edition: OCT 7 2013, DOI
2012
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Solvent-induced changes in dimensionality of praseodymium coordination polymers with diphenylphosphorylvalerate ligand
Polyhedron, year: 2012, volume: 48, edition: 1, DOI
2011
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Luminescence properties of ‘‘double-stranded staircase’’ copper(I) halide coordination polymers with N-containing ligands
New Journal of Chemistry, year: 2011, volume: 35, edition: 4
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Luminescent properties of europium complexes with bis(diphenylphosphino)alkane dioxides
Luminescence, year: 2011, volume: 26, edition: 6, DOI
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Silicophosphate Gels by Nonhydrolytic Condensation Reactions
Year: 2011, type: Conference abstract
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Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands
Polyhedron, year: 2011, volume: 30, edition: 9
2010
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Lanthanide Luminescence
X. pracovní setkání fyzikálních chemiků a elektrochemiků - sborník příspěvků, year: 2010
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LUMINESCENCE PROPERTIES OF COORDINATION POLYMERS CONTAINING BIDENTATE LIGANDS
Year: 2010
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Luminescence properties of europium(III) coordination polymers with bis(diphenylphosphino)alkane dioxides
XIV. International Symposium on Luminescence Spectrometry, year: 2010
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Molecular Metal Alkoxide Phosphates
1st Czech-French Vltava Meeting of Chemistry in Burgundy, year: 2010