Laser ablation synthesis of new gold carbides. From gold-diamond nano-composite as a precursor to gold-doped diamonds. Time-of-flight mass spectrometric study

• Authors: HAVEL Josef; PENA-MENDEZ Eladia; AMATO Filippo; PANYALA Nagender Reddy; BURŠÍKOVÁ Vilma
• Year of publication: 2014
• Type: Article in Periodical
• Magazine / Source: Rapid Communications in Mass Spectrometry
• MU Faculty or unit: Faculty of Science
• web: http://onlinelibrary.wiley.com/doi/10.1002/rcm.6783/abstract
• Doi: http://dx.doi.org/10.1002/rcm.6783
• Field: Analytic chemistry
• Keywords: gold carbides; laser ablation synthesis; mass spectrometry; gold-doped nano-diamonds
• Description: RATIONALE Gold carbides can be produced via laser ablation synthesis (LAS) from mixtures of nano-gold (NG) and various carbonaceous materials. The nano-composite of nano-gold (NG) and nano-diamond (ND) might represent a promising precursor for the generation of new gold carbides. METHODS Time-of-flight mass spectrometry (TOF MS), transmission electron microscopy (TEM) and energy-dispersive X-ray spectroscopy (EDX) were used. The stoichiometry of clusters was determined via modelling of the isotopic patterns and MSn analysis.

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