Publication details
On the Reaction of P4S10 with Hexamethydisilazane
| Authors | |
|---|---|
| Year of publication | 1998 |
| Type | Article in Periodical |
| Magazine / Source | Heteroatom Chem. |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Keywords | phosphorus; sulfides; thiophosphoric acids |
| Description | P4S10 reacts with HMDSN to give SP(NHSiMe3)x(SSiME3)3-x where x = 0-3. These species were shown by 31P NMR spectroscopy to subsequently form cyclic and linear condensation products. The molecular structure of a linear trimer was authenticated by an X-ray diffraction study. |