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On the Reaction of P4S10 with Hexamethydisilazane
Autoři | |
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Rok publikování | 1998 |
Druh | Článek v odborném periodiku |
Časopis / Zdroj | Heteroatom Chem. |
Fakulta / Pracoviště MU | |
Citace | |
Obor | Anorganická chemie |
Klíčová slova | phosphorus; sulfides; thiophosphoric acids |
Popis | P4S10 reacts with HMDSN to give SP(NHSiMe3)x(SSiME3)3-x where x = 0-3. These species were shown by 31P NMR spectroscopy to subsequently form cyclic and linear condensation products. The molecular structure of a linear trimer was authenticated by an X-ray diffraction study. |