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Publication details
1,6-hexanediammonium dihydrogendecavanadate dihydrate, (H3N-(CH2)(6)-NH3)(2)H2V10O28. 2 H2O
Authors | |
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Year of publication | 2001 |
Type | Article in Periodical |
Magazine / Source | Crystal Research and Technology |
MU Faculty or unit | |
Citation | |
Field | Inorganic chemistry |
Keywords | dihydrogendecavanadate; dihydrate; X-ray diffraction; structure analysis; disordered cation; bond-length/bond-number calculation |
Description | The crystal structure of (H3N-(CH2)(6)-NH3)(2)H2V10O28 . 2 H2O consists of dihydrogendecavanadate anion with C-1 symmetry, two 1.6-hexanediammonium cations and two water molecules. The structure has a P (I) over bar space group symmetry with one of the cations in special position; this cation is disordered, The polyanion of most usual protonation type is similar as formed in other known dihydrogendecavanadates. |