
1,6-hexanediammonium dihydrogendecavanadate dihydrate, (H3N-(CH2)(6)-NH3)(2)H2V10O28. 2 H2O
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Rok publikování | 2001 |
Druh | Článek v odborném periodiku |
Časopis / Zdroj | Crystal Research and Technology |
Fakulta / Pracoviště MU | |
Citace | RAKOVSKÝ, E., L. ŽURKOVÁ a Jaromír MAREK. 1,6-hexanediammonium dihydrogendecavanadate dihydrate, (H3N-(CH2)(6)-NH3)(2)H2V10O28. 2 H2O. Crystal Research and Technology. Berlin: A Wiley-VCH Berlin Publication, 2001, roč. 36, č. 3, s. 339-344. ISSN 0232-1300. |
Obor | Anorganická chemie |
Klíčová slova | dihydrogendecavanadate; dihydrate; X-ray diffraction; structure analysis; disordered cation; bond-length/bond-number calculation |
Popis | The crystal structure of (H3N-(CH2)(6)-NH3)(2)H2V10O28 . 2 H2O consists of dihydrogendecavanadate anion with C-1 symmetry, two 1.6-hexanediammonium cations and two water molecules. The structure has a P (I) over bar space group symmetry with one of the cations in special position; this cation is disordered, The polyanion of most usual protonation type is similar as formed in other known dihydrogendecavanadates. |