Publication details

Příprava nových prekurzorů titanosilikátových materiálů

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Title in English Synthesis of new precursors to titanosilicate materials
Authors

BRLEJOVÁ Zuzana PINKAS Jiří ROESKY Herbert W.

Year of publication 2001
Type Article in Proceedings
Conference 53. zjazd chemických spoločností, Zborník príspevkov 2.
MU Faculty or unit

Faculty of Science

Citation
Field Inorganic chemistry
Keywords titanosilicates; building units
Description The titanosilicate molecule containg a cubic Ti4Si4O12 core was treated with a series of alcohols, silanols, phenols, and acids to replace selectively substituents on Ti and Si atoms. The results of these reactions point to a surprisingly inert Si-N bond. The substitutions take place at the isopropoxide groups on titanium. We prepared several new titanosilicate compounds by these reactions.
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